| Molecular Mechanics Study on Asymmetry Catalysis |
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| 作者姓名： | Da Wei GUO Xiao Zhen YANG |
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| 作者单位： | Polymer Physics Laborator. Institute of Chemistry. Chinese Academy of Sciences.Beijing，100080 |
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| 摘 要： | Theasymmetrycatalysisisanimportantchemicalreactionwidelyusedinbiology,pharmacyalldagriculture.Itispreferredtoenantioselectivehydrogenationofmethylpyruvate(MP)oversuppoFtedplatiniumnanoclusters.Cinchonidine(CD)isamodifier,aco-catalysttothereaction.Withoutthemodifier,therewouldbenoenantioselectivitytothehydrogenationofpyruvate.Inordertoobtainbetterunderstandingofthemechanismofthereaction,especiallytheroleofthemoditler,thepresentstudybymolecularmodelinghasbeenperformedandtheresultsarereportedhe…
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Molecular Mechanics Study on Asymmetry Catalysis |
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| Da Wei GUO, Xiao Zhen YANG.Molecular Mechanics Study on Asymmetry Catalysis[J].Chinese Chemical Letters,1999(9). |
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| Authors: | Da Wei GUO Xiao Zhen YANG |
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| Abstract: | A ground state model about an asymmetry hydrogenation of methyl pyruvate over Pt- nanocluster catalyst with a modifier cinconidine has been built. The role of the modifier in thecatalytic process is explained. |
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| Keywords: | molecular mechanics asymmetry catalysis methyl pyruvate Pt-cluster catalyst moditier |
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