Spin crossover in the cyanide-bridged Mo(V)Mn(III) single-chain magnet containing Fe(II) cations |
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| Authors: | Yoon Jung Hee Ryu Dae Won Choi Sang Yup Kim Hyoung Chan Koh Eui Kwan Tao Jun Hong Chang Seop |
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| Institution: | Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-7, 13, Korea. |
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| Abstract: | A 1D Mo(V)Mn(III) chain compound balanced by {FeHC(3,5-Me(2)pz)(3)](2)}(2+) dications was prepared. This complex displays a typical single-chain magnet character associated with the Mo(V)Mn(III) chain and a spin crossover phenomenon arising from cationic Fe(II) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature. |
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