Physical properties of double perovskite compounds ALaVMoO6 (A=Ca, Sr, Ba)—a possible half-metallic antiferromagnetic system

Double perovskite compounds ALaVMoO₆ (A=Ca, Sr, Ba) have been synthesized and their electrical and magnetic properties have been investigated. Magnetization measurements have indicated the possible antiferromagnetic transitions at 120 and 130 K for A=Ca and Sr samples, respectively. Electrical resistivity ρ for this system shows metallic temperature dependence from 300 to 20 K, though the sample with A=Ca shows weak semiconducting behavior in the low temperature region (<70 K). Considering the magnetic and electrical properties and assuming the V³⁺S=1 and Mo⁴⁺S=1 valence and spin states, the samples with A=Ca and Sr can be promising candidates for half-metallic antiferromagnets.