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Equation of state of silicon nitride carbodiimide Si2CN4
Authors:Vladimir L Solozhenko  Marcus Schwarz
Institution:a LPMTM-CNRS, Institut Galilée, Université Paris Nord, F-93430 Villetaneuse, France
b Chemische Materialwissenschaft, Fachbereich Chemie, Universität Konstanz, D-78457 Konstanz, Germany
c Fachbereich Material- und Geowissenschaften, Technische Universität Darmstadt, D-64287 Darmstadt, Germany
Abstract:The lattice parameters of silicon nitride carbodiimide Si2CN4 have been measured up to 8 GPa at room temperature using energy-dispersive X-ray powder diffraction with synchrotron radiation. A fit of the experimental p-V data to the Birch-Murnaghan equation of state yields the values of the bulk modulus of 8.8(2) GPa and its first pressure derivative of 3.4(1). The compression is found to be anisotropic, with the b-axis being significantly more compressible than the a-and c-axes.
Keywords:61  10  Eq  64  64  30  +t
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