IR spectroscopic study of the interaction between trimethylgallium and arsine in the liquid phase |
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| Authors: | P G Sennikov D A Raldugin Sh Sh Nabiev |
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| Institution: | (1) institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, 49 u1. Tropinina, 603600 Nizhnii Novgorod, Russian Federation;(2) Russian Scientific Center  Kurchatov Institute , 1 pl. Akad. Kurchatova, 123182 Moscow, Russian Federation |
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| Abstract: | The formation of a donor-acceptor complex Me3Ga · AsH3 in a solution in liquid krypton at 130 K and in a binary liquid solution of those substances at 263 K was established by IR spectroscopy. In the latter case, Me3Ga and AsH3 react at an appreciable rate to form an amorphous product of composition Me3-x
,GaAsH3-x
.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2259–2262, September, 1996. |
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| Keywords: | trimethylgallium arsine solution donor-acceptor complex IR spectroscopy |
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