Affiliation: | (1) Department of Chemistry, University of Central Florida, Orlando, Florida;(2) College of Optics and Photonics: CREOL & FPCE, University of Central Florida, Orlando, Florida;(3) Institute of Physics, Prospect Nauki, 46, Kiev-28, 03028 Kiev, Ukraine |
Abstract: | The steady-state excitation anisotropy spectra of fluorene derivatives were measured in viscous solvents, under the one- and two-photon excitation, over a broad spectral range (UV–Visible). The orientation of their absorption transition moments for the first, S0S1, and second, S0S2, excited states were determined. It was shown experimentally that a decrease in the angle between S0S1and S0S2 transitions corresponded to an increased value of two-photon absorption (2PA) cross section for these molecules. Two-photon excitation anisotropy was nearly constant over the spectral region investigated (in contrast to one-photon excitation anisotropy spectra) and can be roughly explained by a simple model of 2PA based on the single intermediate state approximation. For comparison, the same trend in two-photon excitation anisotropy was observed for Rhodamine B inglycerol. |