Silaborations of 1,3-enynes - substrate controlled allene/1,3-diene selectivity |
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| Authors: | Lüken Christian Moberg Christina |
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| Affiliation: | KTH School of Chemical Science and Engineering, Organic Chemistry, Stockholm, Sweden. |
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| Abstract: | Silaboration of 1,3-enynes catalyzed by group 10 metal complexes affords 1,3-dienes with vinylborane and vinylsilane functions or 1,2-dienes with allylborane and vinylsilane functions. The type of product formed is determined by the size of the alkyne substituent. |
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