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Reaction of arenediazonium tetrafluoroborates with allyl methacrylate in the presence of the thiocyanate anion
Authors:B D Grishchuk  V S Baranovskii  R V Simchak  G N Tulaidan  P M Gorbovoi
Institution:(1) Gnatyuk National Pedagogical University, ul. M. Krivonosa 2, Ternopol, 46009, Ukraine
Abstract:Allyl 2-thiocyanato-2-methyl-3-arylpropionates were obtained by the reaction of arenediazonium tetrafluoroborates with allyl methacrylate in a water-acetone (1: 5) medium, involving thiocyanatoarylation by the C=C bond of the methacrylic fragment. Under the examined conditions, the allylic fragment of the biunsaturated compound does not react.
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