Cobalt(II),nickel(II) AND zinc(II) dicarboxylate complexes with hydrazine as bridgedligand |
| |
| Authors: | B. N. Sivasankar |
| |
| Affiliation: | (1) Department of Chemistry, Faculty of Science, UAEU, AlAin, , United Arab Emirates, 17551;(2) Department of Chemistry, Faculty of Science, Cairo University (Fayoum), Fayoum, , Egypt;(3) Chemistry Department, University College for Girls, Ain Shams University, Cairo, Egypt |
| |
| Abstract: | The complexes of chromium and molybdenum with salicylidene-2-aminophenol (shaH2), salicylidene-2-aminoanisole (salanH2), salicylidene-2-aminoaniline (salphenH2) and biquinoline (biq) were studied using the thermogravimetric techniques. The thermal decomposition of all complexes was found to be first order reaction and the thermodynamic parameters corresponding to the different decomposition steps were reported. Molybdenum complexes were found to be more thermally stable and the order of stability was [Mo(CO)4(biq)]>[MoO(salphen)]>[MoO2(salphenH)2]>[MoO4(salan)2]>[MoO(sha)]. Similar trend was found for chromium complexes where [Cr(CO)4(biq)]>[Cr(CO)2(salphen)] >[CrO2(CO)2(shaH2)]>[CrO2(CO)2(salan)2]. |
| |
| Keywords: | chromium kinetics of thermal decomposition molybdenum Schiff bases thermogravimetric studies |
| 本文献已被 SpringerLink 等数据库收录！ |
|
