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Li- and V-NMR study of LiVS2
Authors:T Tanaka  Y Kawasaki  Y Ideta  T Ohno  M Nohara  H Takagi
Institution:a Quantum Materials Science, Institute of Technology, Tokushima University, Tokushima 770-8506, Japan
b Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561, Japan
c CREST, Japan Science and Technology Agency, Japan
d The Institute of Physical and Chemical Research (RIKEN), Wako, Saitama 351-0198, Japan
Abstract:7Li- and 51V-NMR have been measured to make clear the electronic state in a two-dimensional triangular lattice LiVS2. Knight shift of both 7Li- and 51V-NMR is almost independent of temperature below the phase transition temperature Tc of about 310 K from the paramagnetic state to non-magnetic state. The 51V- spin-lattice relaxation rate 1/T1 reveals an exponential temperature dependence below Tc, indicating a gap structure of electronic state. These results are consistent with a non-magnetic state with a trimer singlet of V3+ spins below Tc.
Keywords:A  Magnetic materials  D  Magnetic properties  D  NMR
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