| 3,5-二(氨甲基)-1,2,4-三唑的合成与表征 |
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| 引用本文： | 裘灵光,田玉鹏,谢复新,张银汉.3,5-二(氨甲基)-1,2,4-三唑的合成与表征[J].安徽大学学报(自然科学版),1999,23(4):75-80. |
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| 作者姓名： | 裘灵光 田玉鹏 谢复新 张银汉 |
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| 作者单位： | 1. 安徽大学化学系,安徽,合肥,230039
2. 中国科技大学应用化学系,安徽,合肥,230026 |
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| 基金项目： | 国家自然科学基金;29871001; |
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| 摘 要： | 以羟基乙酸与水合肼为原料,经缩合成环、脱氨基、氯化、氨化四步反应,合成了尚未见文献报道的化合物3 ,5 - 二( 氨甲基) - 1 ,2 ,4 - 三唑(amt·2HCl) ,用元素分析、红外光谱、核磁共振氢谱和质谱等方法进行了表征。讨论了合成条件、光谱特性及其质谱裂解途径
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| 关 键 词： | 3 5-二(氨甲基)-1 2 4-三唑 合成 表征 质谱 |
| 文章编号： | 1000-2162(1999)04-0075-06 |
Synthesis and Characterization of 3,5-Bis (aminomethyl)-1,2,4-trizole |
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| QIU Ling-guang ,TIAN Yu-peng ,XIE Fu-xin ,ZHANG Yin-han.Synthesis and Characterization of 3,5-Bis (aminomethyl)-1,2,4-trizole[J].Journal of Anhui University(Natural Sciences),1999,23(4):75-80. |
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| Authors: | QIU Ling-guang TIAN Yu-peng XIE Fu-xin ZHANG Yin-han |
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| Institution: | QIU Ling-guang 1,TIAN Yu-peng 1,XIE Fu-xin 1,ZHANG Yin-han 2 1 |
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| Abstract: | A new compound 3,5-bis(aminomethyl)-1,2,4-trizole(amt) was synthesized in four steps from glycolic acid and hydrazine hydrate by cyclic condensation,deaminizating,chlorinating and ammoniation,and characterized with elemental analysis,IR, 1HNMR and MS. The synthetic conditions of the reaction, character of spectra and splitted rule based MS spectra were also discussed in this paper. |
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| Keywords: | trizole synthesis characterization mass spectra |
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