| 毛细管电泳研究杯[4]吡咯和二吡咯化合物对无机阴离子的识别作用 |
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| 引用本文： | 周长征,邱洪灯,郭勇,蒋生祥.毛细管电泳研究杯[4]吡咯和二吡咯化合物对无机阴离子的识别作用[J].中国化学,2005,23(11):1515-1518. |
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| 作者姓名： | 周长征 邱洪灯 郭勇 蒋生祥 |
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| 作者单位： | Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Graduate School of the Chinese Academy of Sciences, Lanzhou, Gansu 730000, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20275041）. |
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| 摘 要： | Capillary electrophoresis （CE） can separate charged and neutral substances with high speed and efficiency. In this paper, utilizing meso-octamethylcalix4]pyrrole, meso-tetraspirocyclohexylcalJx4]pyrrole, bimethyl bi（2-pyrryl）- methane and 1,1-bi（2-pyrryl）cyclohexane as additives in capillary zone electrophoresis （CZE） electrolyte, their recognition ability to inorganic anions was discussed. The dipyrrylmethanes have better recognition ability than others. Their effects on separation of seven normal inorganic anions by CZE were studied.
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| 关 键 词： | 无机化学 阴离子 吡咯 毛细管 电泳法 |
| 收稿时间： | 2004-11-09 |
| 修稿时间： | 2004-11-092005-07-13 |
Research on Inorganic Anion Recognition of Calix[4]pyrroles and Dipyrrylmethanes by Capillary Zone Electrophoresis |
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| ZHOU,;Chang-Zheng;QIU,;Hong-Deng;GUO,;Yong;JIANG,;Sheng-Xiang.Research on Inorganic Anion Recognition of Calix[4]pyrroles and Dipyrrylmethanes by Capillary Zone Electrophoresis[J].Chinese Journal of Chemistry,2005,23(11):1515-1518. |
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| Authors: | ZHOU ;Chang-Zheng;QIU ;Hong-Deng;GUO ;Yong;JIANG ;Sheng-Xiang |
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| Abstract: | Capillary electrophoresis (CE) can separate charged and neutral substances with high speed and efficiency. In this paper, utilizing meso‐octamethylcalix4]pyrrole, meso‐tetraspirocyclohexylcalix4]pyrrole, bimethyl bi(2‐pyrryl)‐methane and 1,1‐bi(2‐pyrryl)cyclohexane as additives in capillary zone electrophoresis (CZE) electrolyte, their recognition ability to inorganic anions was discussed. The dipyrrylmethanes have better recognition ability than others. Their effects on separation of seven normal inorganic anions by CZE were studied. |
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| Keywords: | calix[4]pyrrole dipyrrylmethane anion recognition capillary electrophoresis inorganic anion |
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