A mechanical "flip-switch". Interconversion between co-conformations of a [2]rotaxane with a single recognition site |
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Authors: | Loeb Stephen J Tiburcio Jorge Vella Sarah J |
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Affiliation: | Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada. loeb@uwindsor.ca |
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Abstract: | [2]Rotaxanes utilising the 1,2-bis(pyridinium)ethane, 24-crown-8 motif can exist in two distinct co-conformations whose relative abundances are solvent dependent. |
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