| PRODUCTION, ISOLATION AND SPECTROSCOPIC STUDIES OF THE ENDOHEDRAL FULLERENE Sc2@C80 （Ⅰ-Ⅲ） |
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| 作者姓名： | ChunruWang LihuaGan ChunliBai HisanoriShinohara |
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| 作者单位： | [1]InstituteofChemistry,,ChineseAcademyofSciences,Beijing100080,P.R.China [2]DepartmentofChemistry,NagoyaUniversity,Nagoya464-8602,Japan |
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| 摘 要： | The isolation of multiple-isomers of Sc2@C80(Ⅰ,Ⅱ,Ⅲ) endohedral metallofullerenes is reported for the first time. The new C80-based Sc-metallofullerenes are characterized by UV-Vis-NIR absorption spectroscopy and detailed chromatographic retention time data. A close relationship between the isomer structure and the corresponding HPLC retention time of the metallofullerenes is presented.
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| 关 键 词： | 超导率 碳 同素异构体 氦气 实验观测 |
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