A potential intermediate for the aza-Corey-Chaykovsky reaction: synthesis, structure, and thermolysis of a pentacoordinate 1,2-thiazetidine 1-oxide |
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| Authors: | Kano Naokazu Daicho Yuya Kawashima Takayuki |
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| Affiliation: | Department of Chemistry, Graduate School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. |
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| Abstract: | Thermolysis of a pentacoordinate 1lambda(6),2-thiazetidine, which was synthesized for the first time and characterized by X-ray crystallographic analysis, gave the corresponding aziridine and a cyclic sulfinate almost quantitatively. The potential intermediacy of a 1lambda(6),2-thiazetidine was suggested in the aza-Corey-Chaykovsky reaction. |
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