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Electronic Fock space as associative superalgebra
Authors:A I Panin
Abstract:A new algebraic structure on a finite dimensional electronic Fock space is studied in detail. This structure is defined in terms of a certain multiplication of many electron wave functions and has close interrelation with coupled cluster and similar approaches. Its study simplifies the mathematical backgrounds of these approaches. Even more, it leads to relations that would be very difficult to derive using conventional technique. Formulas for action of the creation‐annihilation operators on products of state vectors are derived. Explicit expressions for action of simplest particle‐conserving products of the creation‐annihilation operators on powers of state vectors are given. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2006
Keywords:Fock space  commutative and skew‐commutative algebras  configuration interaction  coupled cluster approach
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