| Abstract: | Isosorbide and equimolar amounts of various diols were polycondensed with diphosgene and pyridine. Bisphenol A, 3,3′‐dimethyl bisphenol A, bisphenol C, 1,3‐bis(4‐hydroxybenzoyloxy)propane, and 1,4‐cyclohexane diol were used as comonomers. The compositions were determined by 1H NMR spectroscopy; the random sequences were characterized by 13C NMR spectroscopy. For the high‐molar‐mass copolycarbonates of bisphenol A, 3,3′‐dimethyl bisphenol A, and bisphenol C, matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry proved that the chain growth was mainly limited by cyclization. Copolycarbonates with alternating sequences were obtained by the polycondensation of bisphenol A with isosorbide bischloroformiate or from isosorbide and bisphenol A bischloroformiate. In these cases, large amounts of cyclic oligo‐ and polycarbonates were also formed. The glass‐transition temperatures were determined by differential scanning calorimetry measurements. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3616–3628, 2006 |
