A new layered iron fluorophosphate |
| |
| Authors: | Amitava Choudhury |
| |
| Institution: | (1) Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur PO, 560 064 Bangalore, India;(2) Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012 Bangalore, India |
| |
| Abstract: | A new iron fluorophosphate of the composition, C6N4H21] Fe2F2(HPO4)3]H2PO4]·2H2O,I has been prepared by the hydrothermal route. This compound contains iron fluorophosphate layers and the H2PO4
- anions are present in the interlayer space along with the protonated amine and water molecules. The compound crystallizes
in the monoclinic space group P21/c.(a = 13.4422(10) ?,b = 9.7320(10) ?, c = 18.3123(3) ?, β= 92.1480°,V= 2393.92(5) ?3, Z = 4,M = 719.92,d
calc. = 1.997 g cm-3, R1 = 0.03 andwR
2= 0.09). |
| |
| Keywords: | Open-framework materials layered iron phosphate hydrothermal synthesis |
| 本文献已被 SpringerLink 等数据库收录！ |
|
