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Polysaccharides of Saponin-Bearing Plants. XV. Structure of Glucoarabinogalactan from Acantophyllum Borszczowii Roots
Authors:A D Kurbanova  A O Arifkhodzhaev  D A Rakhimov  A S Shashkov
Institution:(1) Academy of Sciences of the Republic of Uzbekistan, S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Tashkent;(2) Russian Academy of Sciences, N. D. Zelinskii Institute of Organic Chemistry, 117913 Moscow, B-334, Leninskii pr. 47
Abstract:The structure of the branched polysaccharide glucoarabinogalactan was investigated by periodate oxidation, methylation, and 13C NMR spectroscopy. The main chain consists of agr-1rarr6-bonded galactopyranoses. 1rarr2-Bonded D-glucopyranoses and 1rarr3-bonded D-galactopyranoses are located on the unreducing ends. There is a short side chain with beta-1rarr3-bonded L-arabinopyranoses.
Keywords:Acantophyllum Borszczowii  glucoarabinogalactan  structure  oligosaccharide  galactobiose  galactotriose  galactotetrose  galactopentose
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