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Synthesis of tetrathiafulvalene-annulated phthalocyanines |
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| Authors: | Chantal A. Donders Claudia Loosli Antonia Neels |
| Affiliation: | a Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, 3012 Bern, Switzerland b Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux, 51, 2007 Neuchâtel, Switzerland c Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers (CIMMA), UMR 6200 du CNRS, 2 Bd Lavoisier, 49045 Angers, Cedex, France |
| Abstract: | The synthesis of three new TTF-annulated phthalocyanine (Pc) derivatives 5a-c are described. All of them have been characterized by elemental analysis, IR and UV-vis spectroscopy. In all cases, the incorporation of long and flexible aliphatic side-chains into the rigid TTF-annulated Pc core did not promote the formation of a discotic mesophase. |
| Keywords: | Synthesis Tetrathiafulvalene-annulated phthalocyanines Phthalonitrile derivatives Liquid crystal |
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