Stereoselective electrocatalytic transformation of malonate and alkylidenecyanoacetates into (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates |
| |
| Authors: | Michail N. Elinson Sergey K. Feducovich Anatolii N. Vereshchagin Gennady I. Nikishin |
| |
| Affiliation: | a N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991 Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement compounds, ul. Vavilova 28, 119991 Moscow, Russian Federation |
| |
| Abstract: | Electrolysis of malonate and alkylidenecyanoacetates in alcohols in an undivided cell in the presence of NaBr results in stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75-90% yields. |
| |
| Keywords: | Electrolysis Stereoselectivity Electrocatalytic transformation Mediators Malonate Alkylidenecyanoacetates Substituted cyclopropanes |
| 本文献已被 ScienceDirect 等数据库收录！ |
