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Synthesis and reactions of nitro derivatives of hydrogenated cardanol |
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| Authors: | Orazio A. Attanasi Cinzia Fiani Giuseppe Mele |
| Affiliation: | a Centro di Sudio delle Sostanze Organiche Naturali, Facoltà di Scienze Matematiche, Fisiche e Naturali, Università degli Studi di Urbino ‘Carlo Bo’, Via Sasso 75, 61029 Urbino, Italy b Dipartimento di Ingegneria dell'Innovazione, Università di Lecce, Via Arnesano, 73100 Lecce, Italy c Dipartimento di Agrobiologia ed Agrochimica, Università della Tuscia, Via San Camillo de Lellis, 01100 Viterbo, Italy |
| Abstract: | 3-n-Pentadecylphenol (hydrogenated cardanol) and its derivative 5-n-pentadecyl-2-tert-butylphenol can be nitrated using nitric acid in acetonitrile or methanol to give mono, di or trinitro products. 5-n-Pentadecyl-2-nitrophenol undergoes reductive carbonylation to give a benzoxazole-2-one derivative. An efficient catalytic oxidation reaction in the presence of MeReO3 has also been studied. |
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