Use of chiral sulfoxides in asymmetric synthesis |
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| Authors: | Hé lè ne Pellissier [Author Vitae] |
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| Affiliation: | UMR n° 6180, Faculté des Sciences de Saint-Jérôme, Avenue Esc. Normandie-Niemen, 13397 Marseille Cedex 20, France |
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| Abstract: | |
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| Keywords: | Ac, acetyl Acac, acetylacetone AIBN, 2,2&prime -azobisisobutyronitrile Ar, aryl BF3· Et2O, boron trifluoride etherate BINAP, 2,2&prime -bis(diphenylphosphanyl)-1,1&prime -binaphthyl Bn, benzyl Boc, tert-butoxycarbonyl Born, borneol Bu, butyl Cbz, benzyloxycarbonyl Cod, 1,5-cyclooctadiene Cy, cyclohexyl dba, (E,E)-dibenzylideneacetone DBU, 1,8-diazabicyclo[5.4.0]undec-7-ene de, diastereomeric excess DIBAL, diisobutylaluminium hydride DIPEA, diisopropylethylamine DMAD, dimethyl acetylenedicarboxylate DMF, dimethylformamide Dodec, dodecyl dppf, 1,1&prime -bis(diphenylphosphanyl)ferrocene dr, diastereomeric ratio E, electrophile ee, enantiomeric excess Et, ethyl Hex, hexyl HMDS, hexamethyldisilazide isoB, isoborneol LDA, lithium diisopropylamide LHMDS, lithium hexamethyldisilazide LICA, lithium dicyclohexylamine M, metal MA, maleic anhydride m-CPBA, 3-chloroperoxybenzoic acid Me, methyl Ment, menthyl Mes, mesyl MOM, methoxymethyl Naph, naphthyl NMM, N-methylmaleimide NMO, N-methylmorpholine N-oxide NPM, N-phenylmaleimide Pent, pentyl Ph, phenyl Piv, pivaloyl PMB, p-methoxybenzoyl PMP, p-methoxyphenyl Pr, propyl PTAD, phenyltriazolinedione Py, pyridine TBAF, tetra-n-butylammonium fluoride TBDMS, tert-butyldimethylsilyl Tf, trifluoromethanesulphonyl TFAA, trifluoroacetic anhydride THF, tetrahydrofuran THP, tetrahydropyranyl TIP, triisopropylphenyl TIPS, triisopropylsilyl TMS, trimethylsilyl TMSOTf, trimethylsilyl trifluoromethanesulphonate Tol, tolyl Ts, 4-toluenesulphonyl (tosyl) |
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