Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes |
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| Authors: | Alnasleh Bassam K Sherrill William M Rubin Michael |
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| Affiliation: | Department of Chemistry, Univeristy of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-75832, USA. |
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| Abstract: | Novel transition-metal-catalyzed addition of P-H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity. |
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