Synthesis and some properties of vanadocene isocyanate and isothiocyanate d1-complexes |
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| Authors: | A S Gordetsov S V Zimina S E Skobeleva N P Makarenko V K Cherkasov V P Mar'in T N Konkina Yu I Dergunov |
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| Institution: | (1) Institute of Chemistry, Academy of Sciences of the USSR, Gorki;(2) Gorki Medical Institute, USSR |
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| Abstract: | Conclusions Vanadocene monochloride and vanadocene dichloride react with organotin and organosilicon pseudohalides, R3MNCX (R3M=Bu3Sn, Me3Si and X=O, S), to give the corresponding vanadium (IV) d1-complexes, Cp2V(NCX)2 or Cp2VCl(NCX).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 678–681, March, 1988. |
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