B-frame supported bimetallics. [(PMe2ph)2PtB9H11Ru(η-PrC6H4Me)] and [(PMe2ph)2PtB9H9Ru(η-PrC6H4Me)]; an interesting pair of electron-deficient nido and closo geometries期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

*B-frame supported bimetallics. [(PMe₂ph)₂PtB₉H₁₁Ru(η-PrC₆H₄Me)] and [(PMe₂ph)₂PtB₉H₉Ru(η-PrC₆H₄Me)]; an interesting pair of electron-deficient nido* and closo geometries**

Authors:	Young-hee Kim Paul A Cooke Robert Greatrex John D Kennedy Mark Thornton-Pett

Abstract:	[7,7-(PMe₂Ph)₂-9-(η⁶-^isoPrC₆H₄Me)-7,9-PtRuB₉H₁₁] has a formal closo Wadian cluster-electron count, but a nido geometry, whereas [1-(η⁶-^isoPrC₆H₄Me)-4,4-(PMe₂Ph)₂-1-4-RuPtB₉H₉], which does have a closo geometry, has a formal sub-closo cluster electron count; both compounds are formed in the reaction between [6-(η⁶-^isoPrC₆H₄Me)-nido-6 RuB₉H₁₃], KH and [PtCl₂(PMe₂Ph)₂].

Keywords:	Nido and closo geometries Electron count Boron
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