| Ca改性钛酸铅纳米晶的制备及结构研究 |
| |
| 引用本文： | 傅宏刚,于海涛,张新,张艳喜,张志谦,徐崇泉,强亮生.Ca改性钛酸铅纳米晶的制备及结构研究[J].高等学校化学学报,1999,20(8):1271-1275. |
| |
| 作者姓名： | 傅宏刚 于海涛 张新 张艳喜 张志谦 徐崇泉 强亮生 |
| |
| 作者单位： | 1. 黑龙江大学化学化工学院, 哈尔滨 150080;
2. 哈尔滨工业大学应用化学系, 哈尔滨 150001 |
| |
| 基金项目： | 黑龙江省自然科学基金，黑龙江大学杰出青年科学基金 |
| |
| 摘 要： | 用溶胶-凝胶工艺制备了Pb1-xCaxTiO3(0≤x≤0.3)纳米晶,在不同焙烧条件下研究其粉体晶相结构的变化.研究结果表明,升温速度和焙烧温度对纳米粉的晶相、晶胞参数和晶粒尺寸有显著影响.讨论了晶胞参数、四方畸变度和晶胞体积与Ca含量的关系.
|
| 关 键 词： | 钙改性钛酸铅 纳米晶材料 溶胶-凝胶法 晶体结构 |
| 收稿时间： | 1998-09-10 |
Fabrication and Crystalline Structure of Ca Modified Lead Titanate Nanocrystals |
| |
| FU Hong-Gang,YU Hai-tao,ZHANG Xin,ZHANG Yan-Xi,ZHANG Zhi-qian,XU Chong-quan,QIANG Liang-sheng.Fabrication and Crystalline Structure of Ca Modified Lead Titanate Nanocrystals[J].Chemical Research In Chinese Universities,1999,20(8):1271-1275. |
| |
| Authors: | FU Hong-Gang YU Hai-tao ZHANG Xin ZHANG Yan-Xi ZHANG Zhi-qian XU Chong-quan QIANG Liang-sheng |
| |
| Institution: | 1. College of Chemistry and Chemical Engineering, Heilongjiang University, Harbin 150080, China;
2. The Applied Chemistry Department, Harbin Institute of Technology, Harbin 150001, China |
| |
| Abstract: | Calcium modified lead titanate nanocrystal materials have been prepared by using a sol\|gel method. Different thermal treatment conditions have been used for the research of the crystalline structure of Pb\-\{\%1-x\%\}Ca\-\%x\%TiO\-3 powders. The lattice parameters and \%c/a\% ratios were determined by using XRD method. The grain sizes of powders were detected by TEM photographs and X\|ray diffraction. The influence of thermal treatment conditions on crystalline structure, lattice parameters, tetragonolity(\%c/a\%) and the relationships of \%a, c, c/a\% with Ca content were discussed. WT5HZ] |
| |
| Keywords: | Calcium modified lead titanate Nanocrystal materials Sol\|gel method Crystalline structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
