| 高强度疏水缔合水凝胶的交联网络结构形成机理 |
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| 引用本文： | 姜国庆,刘凤岐. 高强度疏水缔合水凝胶的交联网络结构形成机理[J]. 功能高分子学报, 2011, 24(1): 43-48 |
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| 作者姓名： | 姜国庆 刘凤岐 |
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| 作者单位： | 姜国庆,JIANG Guo-qing(大庆油田有限责任公司勘探开发研究院采收率研究一室,黑龙江,大庆,163712);刘凤岐,LIU Feng-qi(吉林大学化学学院,长春,130012) |
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| 基金项目： | 黑龙江省自然科学基金青年科学基金项目 |
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| 摘 要： | 高强度疏水缔合水凝胶(HA-gels)是丙烯酰胺(AM)和少量的疏水单体辛基酚聚氧乙烯(4)醚丙烯酸酯(OP-4-AC)在十二烷基硫酸钠(SDS)水溶液中采用胶束共聚的方法制备的.采用胶束共聚理论、橡胶弹性统计理论及Mooney-Rivlin理论,并结合单向拉伸实验数据,对HA-gels的交联网络结构的形成机理进行了探...
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| 关 键 词： | 疏水缔合水凝胶 胶束共聚 交联网络 形成机理 |
Formation Mechanism of Cross-Linked Network Structure of Hydrophobic Association Hydrogels with High Mechanical Strength |
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| JIANG Guo-qing,LIU Feng-qi. Formation Mechanism of Cross-Linked Network Structure of Hydrophobic Association Hydrogels with High Mechanical Strength[J]. Journal of Functional Polymers, 2011, 24(1): 43-48 |
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| Authors: | JIANG Guo-qing LIU Feng-qi |
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| Affiliation: | JIANG Guo-qing~1,LIU Feng-qi~2 (1.The First Enhanced Oil Recovery Laboratory,Exploration and Development Research Institute,Daqing Oilfield Company Limited,Daqing 163712,Heilongjiang,China,2.College of Chemistry,Jilin University,Changchun 130012,China) |
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| Abstract: | Hydrophobic association hydrogels(HA-gels) with high mechanical strength were successfully prepared through micellar copolymerization of acrylamide(AM) and small amount of octylphenol polyoxyethylene acrylate(OP-4-AC) in an aqueous solution containing sodium dodecyl sulfate(SDS).On the basis of the micellar copolymerization theory,the statistical molecular theory of rubber elastic,the Mooney-Rivlin theory,and using uniaxial stretching data,formation mechanism of cross-linked network structure of HA-gels wer... |
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| Keywords: | hydrophobic association hydrogels micellar copolymerization cross-linked network formation mechanism |
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