New triple-decker complexes prepared by the stacking reactions of cationic metallofragments with sandwich compounds |
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Authors: | A. R. Kudinov M. I. Rybinskaya |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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Abstract: | The results of our recent studies devoted to the synthesis of cationic triple-decker complexes are summarized. The stacking reactions of cationic metallofragments with sand-with compounds can be used as a general method for the synthesis of these complexes. This method was used for the preparation of 30- and 34-electron cationic triple-decker complexes containing cyclopentadienyl and pentaphospholyl ligands in the bridging position and carbocycles C n H n (n=4–7) and carboranes as terminal ligands. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1636–1642, September, 1999. |
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Keywords: | sandwich compounds triple-decker complexes |
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