A reassignments of the EPR spectrum attributed to the radical cation of 2,2,3,3-tetramethylbutane |
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Authors: | Jih Tzong Wang Ffrancon Williams |
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Affiliation: | Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37916, USA |
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Abstract: | The EPR spectrum of γ-irradiated 2,2,3,3-tetramethylbutane has been reinvestigated. Previous evidence for the radical cation Me3C??CMe+3 has been critically examined and it is concluded that a more satisfactory analysis can be made on the basis of the three neutral radicals ?CH2CMe2CMe3, ?CMe2CMe3 and ?CMe3. |
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