Synthesis of benzothiophenes in gas phase from aromatic hydrocarbons and carbon disulfide |
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Authors: | S Esteban J M Marinas M P Martinez-Alcazar M Martinez and A R Agarrabeitia |
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Institution: | (1) Department of Organic Chemistry, Faculty of Chemistry, Complutense University of Madrid, Ciudad Universitaria, 280040 Madrid;(2) Department of General Chemistry and macromolecules, U.N.E.D., Ciudad Universitaria, 280040 Madrid;(3) Department of Organic Chemistry, Faculty of Sciences, University of Córdoba, Avda. Medina Azahara s/n, Cordoba, Spain |
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Abstract: | A way of synthesis of benzothiophenes, in the gas phase, employing a monosubstituted aromatic compound, carbon disulfide as sulfur source and a Kearby type aluminium orthophosphate as catalyst, has been studied. The best yields in benzothiophene (53%) were reached when vinylbenzene was employed, in a very selective reaction.
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