Twelve-connected porous metal-organic frameworks with high H(2) adsorption |
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| Authors: | Jia Junhua Lin Xiang Wilson Claire Blake Alexander J Champness Neil R Hubberstey Peter Walker Gavin Cussen Edmund J Schröder Martin |
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| Affiliation: | School of Chemistry, University of Nottingham, University Park, Nottingham, UK. |
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| Abstract: | The twelve-connected metal-organic frameworks {[Ni(3)(OH)(L)(3)].n(solv)}(infinity) and {[Fe(3)(O)(L)(3)].n(solv)}(infinity) [LH(2) = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H(2) up to 4.15 wt% at 77 K. |
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