Mass spectrometric investigation of the coordination compounds of nickel(II) and palladium(II) by using their 1,2-hydroxylamineoxime derivatives |
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| Authors: | K M Indrichan N V Gérbéléu S V Larionov |
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| Institution: | 1. Institute of Chemistry, Academy of Sciences of the Moldavian SSR, Kishinev
2. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk
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| Abstract: | | 1. |
The dissociative ionization of spin-coupled bis-chelates of Ni(II) and Pd(II) with derivatives of 1,2-hydroxylaminoxime differs very little from the behavior of coordination compounds with ligands of the nonradical type.
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The difference in the fragmentation of Ni(II) and Pd(II) complexes is due to the greater ability of palladium to form ions containing a  bond and also its smaller affinity toward oxygen.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 53–55, January, 1989. |
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