J(Si,H) Coupling Constants in Nonclassical Transition‐Metal Silane Complexes |
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| Authors: | Prof. Dr. Wolfgang Scherer M. Sc. Petra Meixner Dipl.‐Phys. Kilian Batke Dr. José E. Barquera‐Lozada Prof. Dr. Klaus Ruhland M. Sc. Andreas Fischer Dr. Georg Eickerling Dr. Klaus Eichele |
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| Affiliation: | 1. Institut für Physik, Universit?t Augsburg, Augsburg, Germany;2. Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Mexico;3. Institut für Anorg. Chemie, Universit?t Tübingen, Tübingen, Germany |
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| Abstract: | We will outline that the sign and magnitude of J(Si,H) coupling constants provide a highly sensitive tool to measure the extent of Si?H bond activation in nonclassical silane complexes. Up to now, this structure–property relationship was obscured by erroneous J(Si,H) sign determinations in the literature. These new findings also help to identify the salient control parameters of the Si?H bond activation process in nonclassical silane complexes. |
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| Keywords: | charge density coupling constants MO analysis NMR spectroscopy nonclassical silane complexes |
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