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Complex Formation in Electrolyte Solutions in the Course of Plating Protective Coatings on Titanium
Authors:Gnedenkov  S V  Khrisanfova  O A  Zavidnaya  A G  Sinebryukhov  S L  Kon'shin  V V  Bulanova  S B  Gordienko  P S
Institution:(1) Institute of Chemistry, Far Eastern Division, Russian Academy of Sciences, Vladivostok, Russia
Abstract:Conditions for complex formation in aqueous electrolyte solutions containing salts of aluminum and hydroxy carboxylic acids were studied by 2 7Al and 1 9F NMR spectroscopy. The formation of complex anions in the electrolytes at various pH and their discharge on the anode under conditions of a microplasma process allowed preparation of surface layers containing agr-Al2O3 on VT1-0 titanium. The interrelation between the composition and properties of the coatings was studied.
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