Colloidal Nanoparticles: Formation of Large 2D Arrays of Shape‐Controlled Colloidal Nanoparticles at Variable Interparticle Distances (Part. Part. Syst. Charact. 1/2013) |
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Authors: | Simon Ullrich Sebastian P. Scheeler Claudia Pacholski Joachim P. Spatz Stefan Kudera |
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Affiliation: | Max‐Planck Institute for Intelligent Systems, Department of New Materials and Biosystems & University of Heidelberg, Department of Biophysical Chemistry, Heisenbergstr. 3, 70569 Stuttgart, Germany |
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Abstract: | A method for the production of homogeneous layers of nanoparticles of arbitrary shape is presented. The method relies on a ligand exchange with a functionalized polymer and a subsequent self‐assembly of a thin film on the substrates. The interparticle distances in the layer can be adjusted by the length of the polymer. In the case of spherical particles, the approach yields quasi‐hexagonal structures; in the case of anisotropic particles, the minimum distance between adjacent particles is controlled. Regular arrangements of the nanoparticles covering areas of several square centimeters are achieved. |
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Keywords: | gold nanoparticles gold nanorods polystyrene self‐assembly 2D arrays |
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