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High‐temperature thermoelectric properties of p‐type skutterudites Ybx Co3FeSb12
Authors:Yongkwan Dong  Pooja Puneet  Terry M Tritt  George S Nolas
Institution:1. Department of Physics, University of South Florida, Tampa, FL 33620, USA;2. Department of Physics and Astronomy, Kinard Laboratory, Clemson University, Clemson, SC 29634, USA
Abstract:Partially filled polycrystalline p‐type skutterudites of nominal compositions Ybx Co3FeSb12 were synthesized and their thermoelectric properties characterized. The compositions and filling fractions were confirmed with a combination of Rietveld refinement and elemental analysis. The thermoelectric properties were evaluated from 300 K to 810 K. The Seebeck coefficient and resistivity increase while the thermal conductivity decreases with increasing Yb content. A maximum ZT value of 0.85 was obtained at 810 K. This work is part of a continuing effort to enhance the thermoelectric properties of p‐type skutterudites, as this class of materials continues to be of interest for thermoelectrics applications. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Keywords:thermoelectric properties  skutterudites  ytterbium  antimonide
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