Mechanism of oxidation of cyclohexane by the radical cation of pyridine N-Oxide |
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| Authors: | S. I. Kulakovskaya S. N. Shamaev V. M. Berdnikov |
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| Affiliation: | (1) N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR |
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| Abstract: | Oxidation of pyridine N-oxide in the presence of cyclohexane was studied on platinum and carbon glass rotating disk electrodes using the method of cyclic voltammetry in 0.2 N LiClO4 in acetonitrile. It was hypothesized that the electrochemically generated N-oxide radical cation reacts with cyclohexane according to the mechanism of hydrogen atom cleavage.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1488–1491, July, 1990. |
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