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Isothermal vapor–liquid equilibrium data for the binary mixture difluoromethane (HFC-32) + ethyl fluoride (HFC-161) over a temperature range from 253.15 K to 303.15 K
Authors:Xiao-hong Han  Zan-jun GaoYing-jie Xu  Yu QiuXu-wei Min  Qin WangGuang-ming Chen
Institution:Institute of Refrigeration and Cryogenics, State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China
Abstract:Isothermal vapor–liquid equilibrium data of difluoromethane (HFC-32) + ethyl fluoride (HFC-161) mixture in the range of temperatures from 253.15 K to 303.15 K have been measured in the wide range of compositions. The experimental method used for this work is the single-cycle type. Using Peng–Robinson (PR) equation of state, combined with the first Modified Huron-Vidal (MHV1) mixing rule and Wilson model, the vapor–liquid equilibrium data are correlated. The correlation results have a good agreement with the experiment results. The average absolute vapor composition deviation is within 0.0125, and its largest absolute deviation of the vapor composition is 0.0568; the average relative pressure deviation is within 0.76% and its largest relative pressure deviation is 2.87%. In addition, the results reveal that there is no azeotrope in the binary system, and their temperature glides are small.
Keywords:Alternative refrigerants  HFC-161  Vapor&ndash  liquid equilibrium  Mixing rule  Equation of state
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