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Kinetic of hydrate formation of propane and its mixture with methane in a circulating flow reactor
Authors:M Sarshar  J Fathikalajahi  F Esmaeilzadeh
Institution:1. Fars Engineering Research Center, Institute of Engineering, Shiraz, Iran;2. Chemical and Petroleum Engineering Department, School of Engineering, Shiraz University, Shiraz, Iran;3. Petroleum & Chemical Engineering Department, Sultan Qaboos University, Oman;4. School of Chemical Engineering, Shiraz University of Technology, Shiraz, Iran
Abstract:Kinetics of hydrate formation for propane and its mixture with 73% methane have been studied experimentally and theoretically at pressure up to 2 MPa and temperature up to 277.65 K in a 10 m circulating flow reactor. A mathematical model has been developed for the process of hydrate formation based on crystallization, mass transfer and thermodynamics concepts. The amounts of gas consumptions due to hydrate formation are measured experimentally and predicted by the model. The agreement between the experimental measured gas consumptions and predicted values by the mathematical model are very good and the average deviation errors in the prediction of gas consumption are less than 10%.
Keywords:Kinetics  Gas hydrate  Circulating flow reactor  Modeling  Simulation
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