Solubilities of ammonia in basic imidazolium ionic liquids |
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Authors: | Guihua Li Qing Zhou Xiangping Zhang LeiWang Suojiang Zhang Jianwei Li |
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Institution: | 1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100190, China;2. State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, PR China |
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Abstract: | Solubilities of ammonia in four conventional imidazolium ionic liquids: Cnmim]BF4] (n = 2, 4, 6, 8) have been measured. Isothermally fixed temperatures are 293.15, 303.15, 313.15, 323.15 and 333.15 K; the pressure is from 0 to 1.0 MPa. High solubilities of ammonia are found, and it is also found that the solubilities of ammonia increase when the length of cations’ alkyl increases (the ILs have the same anion), that is: C8mim]+ > C6mim]+ > C4mim]+ > C2mim]+. The solubility data have been correlated by the Krichevisky–Kasarnovsky equation, and then Henry's constants and partial molar volumes of NH3 at infinite dilution are obtained. The thermodynamic properties such as solution enthalpy (ΔsolH), solution Gibbs free energy (ΔsolG), solution entropy (ΔsolS), and solution heat capacity (ΔsolCp) of these systems are obtained. |
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Keywords: | Ionic liquids Solubility Fluid phase equilibrium Thermodynamic properties |
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