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| An Improved Synthesis of dl-Muscone | |
| 摘 要： | Muscone.aprincipalodoriferousconshtUent,wasisolatedb3WaIbauminl9O6frOmmuskPodobtainedfromthemalcmuskdeerMo,9cusmoschghnJ'],anditSsthectUret`asdetenninedas(R)-(-)-3-methyl-q'lopentadeCano.eI2l.AnlongnumerousSynthehcmethodsformusconesofarrePOrtedl'-'].theclassicaloneisintramolecularaldolcondensahonof2,l5-hexadecanedjonecamedoutb}'M.Stolllo].However,theshortryntheticschemehasbenhadtwoinherentproblems.ThefirstproblemisagndSynthehcmethodforthedsetone3andthesecondoneisagoodmethodofaldolconde… |
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