CoO/SrTiO3的合成及光催化分解水制氢性能

通过添加碱金属化合物矿化剂,以Sr(NO3)2和钛酸四丁酯的水解产物TiO(OH)2为原料进行固态反应,制得结晶完整性较好的SrTiO3粉末.再由浸渍法负载CoO,制备出光催化分解水催化剂CoO/SrTiO3,在400 W高压汞灯照射下,产氢速率可达到480μmol•g cat－1•h－1. SEM、UV-Vis漫反射光谱表征结果显示,合成SrTiO3时加入KOH矿化剂可使固态反应完全,SrTiO3结晶完整性提高,进而促进其光催化活性提高.确定了适宜的KOH矿化剂用量为2.0％(w).

Synthesis and Properties of CoO/SrTiO3 for the Photocatalytic Decomposition of Water

SrTiO3 powder with high crystal perfection was synthesized by solid-state reaction of strontium nitrate with TiO(OH)2 formed by hydrolysis of tetra-butoxy titanium in the presence of alkali metal compound mineralizer. Then a photocatalyst, CoO/SrTiO3, was prepared by impregnation method. The effect of the mineralezers is decreased in the following order :KOH > NaOH > NaNO3 > KNO3.The photocatalytic activity of CoO/SrTiO3,was increased for ca.8 times when KOH mineralizer was added, with the irradiation of 400 W high-pressure mercury lamp, the hydrogen-generation rate amounts to 480 μmol•g cat－1•h－1 over the CoO/SrTiO3,catalyst.Characterization results from SEM and UV-Vis diffuse reflection spectra analysis show that the solid-state reaction for synthesizing SrTiO3 proceeds completely and the crystal perfection of SrTiO3 is improved by adding KOH mineralizer. The suitable amount of KOH is 2.0％(w).