Transformations of eucarvone and eucarvole oxides in the presence of acids |
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| Authors: | A. N. Karaseva G. A. Bakaleinik Z. G. Isaeva |
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| Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions The eucarvone and eucarvole oxides are opened by acids at the C3-O bond with a retention of the carbon structure. The stereospecific trans-1,2-opening of the epoxide ring is observed in the first case; the cis-1,2-opening and 1,4-addition also occurs in the second case.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 672–674, March, 1984. |
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