Synthesis and characterization of a novel silane-based vinylic monomer and its application in the multilayer core-shell latex |
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Authors: | Hamid Javaherian Naghash Feyzollah Shafie |
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Institution: | 1. Department of Chemistry, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Isfahan, Iran
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Abstract: | A novel monomer methacrylamidophenoxy dimethylsiloxy phenylphthalimide was obtained by a reaction of 4,4′-bis-aminophenoxy dimethylsilane, phthalic anhydride and methacryloyl chloride. Then it has been used in the synthesis of phase-separated polymer latex with a multilayer core-shell morphology by surface cross-linking emulsion polymerization. Poly(butyl acrylate) was used for the seed and the core of the latex, the inner shell was poly(butyl acrylate/styrene) cross-linked with divinylbenzene to avoid phase inversion, and the poly(methyl methacrylate/butyl acrylate/methacrylamidophenoxy dimethylsiloxy phenylphthalimide) was the outer shell. The structural elucidation of monomer was carried out by elemental analysis, FTIR, 1H NMR, and 13C NMR spectroscopic techniques. The morphology and glass transition temperatures of the synthesized product were investigated by transmission electron microscopy and differential scanning calorimetry, respectively. The multilayer core-shell structure was clearly shown in TEM micrographs, and the three-phase separation was confirmed by DSC analysis. The obtained results demonstrated that the average particle size is 81.8, 108 and 132 nm for the core, core-shell and multilayer core-shell particles, which agrees with the TEM micrograph measurement of 75, 103, and 131 nm, respectively. |
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