Stabilization of fluorescent silver clusters by RNA homopolymers and their DNA analogs: C,G versus A,T(U) dichotomy |
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Authors: | Schultz Danielle Gwinn Elisabeth |
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Affiliation: | Chemistry Department, UCSB, Santa Barbara, CA 93117, USA. |
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Abstract: | Single-stranded RNAs host fluorescent silver nanoclusters, analogous to previously studied Ag:DNAs. C and G homopolymers stabilize visible- to IR-emitting silver complexes at neutral pH in both RNA and DNA, but A and T/U do not. Cluster fluorescence is sensitive to sugar as well as base type. |
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