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农膜光转换添加剂的XPS剖析
引用本文:孙海珍,王水菊,陈谋智,陈松岩,蔡加法.农膜光转换添加剂的XPS剖析[J].分析测试学报,2005,24(6):21-24,28.
作者姓名:孙海珍  王水菊  陈谋智  陈松岩  蔡加法
作者单位:厦门大学,化学系,福建,厦门,361005;厦门大学,分析测试中心,福建,厦门,361005;厦门大学,固体表面物理化学国家重点实验室,福建,厦门,361005;厦门大学,分析测试中心,福建,厦门,361005;厦门大学,物理系,福建,厦门,361005
基金项目:福建省自然科学基金;厦门大学校科研和教改项目
摘    要:报道了无保护气氛条件下,采用高温固相还原法合成适用于农用塑料地膜的光转换添加剂,共掺铜、铕激活剂的硫化钙(CaS)无机荧光材料,用X射线光电子能谱(XPS)方法对光转换添加剂中不同工艺下激活剂元素进行表征,再通过光致发光谱、透射光谱测量,探索材料中激活剂的能量传输特性,为高新农业的发展提供清洁能源.

关 键 词:硫化钙  光转换添加剂  激活剂
文章编号:1004-4957(2005)06-0021-04
收稿时间:2004-11-02
修稿时间:2004-11-022005-08-02

XPS Dissection of the Optical Transition Additive in Farm Film
SUN Hai-zhen,WANG Shui-ju,CHEN Mou-zhi,CHEN Song-yan,CAI Jia-fa.XPS Dissection of the Optical Transition Additive in Farm Film[J].Journal of Instrumental Analysis,2005,24(6):21-24,28.
Authors:SUN Hai-zhen  WANG Shui-ju  CHEN Mou-zhi  CHEN Song-yan  CAI Jia-fa
Institution:1. Department of Chemistry, Xiamen University, Xiamen 361005, China; 2. State Key Laboratory for Physics Chemistry of Solid Surface, Xiamen University, Xiamen 361005, China; 3. Analysis and Testing Centre, Xiamen University, Xiamen 361005, China; 4. Department of Physies, Xiamen University, Xiamen 361005, China
Abstract:An optical transition additive used in farm film was synthesized by doping the Cu and Eu activators into an inorganic fluorescent material, CaS with the high-temperature solid phase reduction method under unprotected atmosphere. The characteristics of the activators in the films prepared under different conditions were measured by X-ray photo-electron spectroscopy. The energy-transfer properties of the activators in the films were investigated by the photo-induced luminescence spectra and transmission spectra. It is useful for developing a clean energy source in agriculture.
Keywords:CaS  Optical transition additive  Activator
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