Beiträge zur Chemie der Oxidhalogenide von Molybdän und Wolfram. VI. Thermische Zersetzung von MoCl3 und MoOCl2 |
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| Authors: | H. Oppermann,G. St ver |
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| Affiliation: | H. Oppermann,G. Stöver |
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| Abstract: | The temperature dependence of the thermal decay of α-MoCl3 was determined and the entropies of MoCl3 and MoCl2 calculated. The decomposition behaviour of MoOCl2 under equilibrium conditions may be described by the equation  The decomposition reactions 6 MoOCl2,s = Mo + MoO2 + 4 MoOCl3,g has only inferior importance. From the results the enthalpy and entropy values of MoOCl2 are derived (data see “Inhaltsübersicht”). |
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