Tetrachloro (NN-dimethylformamide) (dimethylsulphoxide) TIN (IV) revisited |
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| Affiliation: | 1. Dpt. Electroquímica, Universidad Autónoma, 28049-Madrid Spain;2. Dpt. Química Inorgánica, Universidad Autónoma, 28049-Madrid Spain;1. Instituto de Energías Renovables, Universidad Nacional Autónoma de México, Temixco, Morelos, 62580, Mexico;2. Centro Universitario de Los Valles (CUValles), Universidad de Guadalajara, Carretera Guadalajara - Ameca Km. 45.5, C.P, 46600, Ameca, Jalisco, Mexico;3. Centro de Investigaciones en Ingeniería y Ciencias Aplicadas, Universidad Autónoma Del Estado de Morelos, Cuernavaca, Morelos, 62209, Mexico;1. Division of Computational Physics, Institute for Computational Science, Ton Duc Thang University, Ho Chi Minh City, Vietnam;2. Faculty of Electrical & Electronics Engineering, Ton Duc Thang University, Ho Chi Minh City, Vietnam;3. Department of Electrical Engineering and Electronics, Don State Technical University, 1 Gagarin Square, 344010 Rostov-on-Don, Russian Federation;4. Department of Computational Technique and Automated System Software, Don State Technical University, 1 Gagarin Square, 344010 Rostov-on-Don, Russian Federation;5. Faculty of Engineering, Vietnamese German University, Thu Dau Mot City, Binh Duong Province, Vietnam;6. Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, 3 Krzhyzhanivsky Street, 03142, Kyiv, Ukraine;7. Department of Inorganic and Physical Chemistry, Lesya Ukrainka Eastern European National University, 13 Voli Avenue, 43025, Lutsk, Ukraine;1. School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510006, China;2. Institute for Solar Energy Systems, Guangdong Provincial Key Laboratory of Photovoltaic Technology, School of Physics, Sun Yat-sen University, Guangzhou 510006, China;1. State Key Lab of Superhard Material and College of Physics, Jilin University, Changchun 130012, China;2. Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China;3. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun, 130022, China;4. College of Physics, Jilin Normal University, Siping, 136000, China;5. State Key Lab of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033, China;1. Department of Physics, Sogang University, Seoul 04107, Korea;2. Convergence Research Center for Solar Energy, DGIST, Daegu 42988, Korea;3. Department of Chemical Engineering and Technology, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea |
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| Abstract: | The previously reported mixed ligand compound SnCl4 (DMF) (DMSO) (DMF=NN-Dimethylformamide, DMSO=Dimethylsulphoxide) has been studied by IR, Raman and Mössbauer spectroscopy. Our results confirm its homogeneity with the DMF and DMSO ligands coordinating in cis position through the oxygen atoms. The compound does not isomerize when heated to 135 C, but decomposes giving rise to cis-SnCl4(DMSO)2 and trans-SnCl4 (DMF)2. |
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