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Infrared spectra of cis-[Pd(CN)2(NH3)2]
Affiliation:1. Department of Biological Sciences, Kent State University, Kent, OH, United States;2. Department of Chemistry and Biochemistry, Kent State University, Kent, OH, United States;3. Department of Environmental and Occupational Health, University of Pittsburgh, Pittsburgh, PA, United States;4. Department of Critical Care Medicine, University of Pittsburgh, Pittsburgh, PA, United States
Abstract:The infrared spectrum of the title compound was recorded at room and liquid—nitrogen temperature and correlated with the available crystallographic data. In order to clarify the origin of some of the low-frequency bands an approximate normal-coordinate analysis was carried out. The appearance of multiple bands in the NH3 bending region was tentatively explained by taking into account the details about the environment of the ammonia ligands.
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